全文获取类型
收费全文 | 20567篇 |
免费 | 234篇 |
国内免费 | 120篇 |
专业分类
安全科学 | 512篇 |
废物处理 | 888篇 |
环保管理 | 2754篇 |
综合类 | 3381篇 |
基础理论 | 5815篇 |
环境理论 | 10篇 |
污染及防治 | 5291篇 |
评价与监测 | 1280篇 |
社会与环境 | 858篇 |
灾害及防治 | 132篇 |
出版年
2021年 | 136篇 |
2019年 | 127篇 |
2018年 | 234篇 |
2017年 | 250篇 |
2016年 | 401篇 |
2015年 | 306篇 |
2014年 | 467篇 |
2013年 | 1598篇 |
2012年 | 573篇 |
2011年 | 815篇 |
2010年 | 666篇 |
2009年 | 661篇 |
2008年 | 829篇 |
2007年 | 863篇 |
2006年 | 765篇 |
2005年 | 662篇 |
2004年 | 647篇 |
2003年 | 628篇 |
2002年 | 610篇 |
2001年 | 764篇 |
2000年 | 575篇 |
1999年 | 325篇 |
1998年 | 261篇 |
1997年 | 274篇 |
1996年 | 277篇 |
1995年 | 331篇 |
1994年 | 302篇 |
1993年 | 280篇 |
1992年 | 276篇 |
1991年 | 278篇 |
1990年 | 294篇 |
1989年 | 277篇 |
1988年 | 249篇 |
1987年 | 241篇 |
1986年 | 222篇 |
1985年 | 200篇 |
1984年 | 255篇 |
1983年 | 210篇 |
1982年 | 271篇 |
1981年 | 219篇 |
1980年 | 184篇 |
1979年 | 201篇 |
1978年 | 184篇 |
1977年 | 153篇 |
1976年 | 138篇 |
1975年 | 143篇 |
1974年 | 159篇 |
1973年 | 162篇 |
1972年 | 148篇 |
1971年 | 146篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
992.
Juan M. González Benítez J. Neil Cape Mathew R. Heal Netty van Dijk Alberto Vidal Díez 《Atmospheric environment (Oxford, England : 1994)》2009,43(26):4087-4094
Water soluble organic nitrogen (WSON) compounds are ubiquitous in precipitation and in the planetary boundary layer, and therefore are a potential source of bioavailable reactive nitrogen. This paper examines weekly rain data over a period of 22 months from June 2005 to March 2007 collected in 2 types of rain collector (bulk deposition and “dry + wet” deposition) located in a semi-rural area 15 km southwest of Edinburgh, UK (N55°51′44″, W3°12′19″). Bulk deposition collectors are denoted in this paper as “standard rain gauges”, and they are the design used in the UK national network for monitoring precipitation composition. “Dry + wet” deposition collectors are flushing rain gauges and they are equipped with a rain detector (conductivity array), a spray nozzle, a 2-way valve and two independent bottles to collect funnel washings (dry deposition) and true wet deposition. On average, for the 27 weekly samples with 3 valid replicates for the 2 types of collectors, dissolved organic nitrogen (DON) represented 23% of the total dissolved nitrogen (TDN) in bulk deposition. Dry deposition of particles and gas on the funnel surface, rather than rain, contributed over half of all N-containing species (inorganic and organic). Some discrepancies were found between bulk rain gauges and flushing rain gauges, for deposition of both TDN and DON, suggesting biological conversion and loss of inorganic N in the flushing samplers. 相似文献
993.
Jason A. Dittman James B. Shanley George R. Aiken Janet E. Towse 《Environmental pollution (Barking, Essex : 1987)》2009,157(6):1953-1956
Stream water samples were collected over a range of hydrologic and seasonal conditions at three forested watersheds in the northeastern USA. Samples were analyzed for dissolved total mercury (THgd), DOC concentration and DOC composition, and UV254 absorbance across the three sites over different seasons and flow conditions. Pooling data from all sites, we found a strong positive correlation of THgd to DOC (r2 = 0.87), but progressively stronger correlations of THgd with the hydrophobic acid fraction (HPOA) of DOC (r2 = 0.91) and with UV254 absorbance (r2 = 0.92). The strength of the UV254 absorbance-THgd relationship suggests that optical properties associated with dissolved organic matter may be excellent proxies for THgd concentration in these streams. Ease of sample collection and analysis, the potential application of in-situ optical sensors, and the possibility for intensive monitoring over the hydrograph make this an effective, inexpensive approach to estimate THgd flux in drainage waters. 相似文献
994.
Ivan Kourtchev Iustinian Bejan John R. Sodeau John C. Wenger 《Atmospheric environment (Oxford, England : 1994)》2009,43(20):3182-3190
The gas-phase ozonolysis of (E)-β-farnesene was investigated in a 3.91 m3 atmospheric simulation chamber at 296 ± 2 K and relative humidity of around 0.1%. The relative rate method was used to determine the reaction rate coefficient of (4.01 ± 0.17) × 10?16 cm3 molecule?1 s?1, where the indicated errors are two least-squares standard deviations and do not include uncertainties in the rate coefficients for the reference compounds (γ-terpinene, cis-cyclooctene and 1,5-cyclooctadiene). Gas phase carbonyl products were collected using a denuder sampling technique and analyzed with GC/MS following derivatization with O-(2,3,4,5,6-pentafluorobenzyl) hydroxylamine (PFBHA). The reaction products detected were acetone, 4-oxopentanal, methylglyoxal, 4-methylenehex-5-enal, 6-methylhept-5-en-2-one, and (E)-4-methyl-8-methylenedeca-4,9-dienal. A detailed mechanism for the gas-phase ozonolysis of (E)-β-farnesene is proposed, which accounts for all of the products observed in this study. The results of this work indicate that the atmospheric reaction of (E)-β-farnesene with ozone has a lifetime of around 1 h and is another possible source of the ubiquitous carbonyls, acetone, 4-oxopentanal and 6-methylhept-5-en-2-one in the atmosphere. 相似文献
995.
A.M.M. Manders M. Schaap R. Hoogerbrugge 《Atmospheric environment (Oxford, England : 1994)》2009,43(26):4050-4059
Since particulate matter has a direct and adverse impact on public health, a good air quality forecast is important. Several European countries presently use statistical forecasting models, which have their limitations, especially for PM10. An alternative approach is to use a chemistry transport model. Here, the ability of the chemical transport model LOTOS-EUROS to forecast PM10 concentrations in the Netherlands was investigated. LOTOS-EUROS models several PM10 components individually. For sulphate, nitrate and ammonium aerosol the evaluation against observations shows that the modelled annual mean concentrations are within 20% of the measured concentration and that the temporal correlation is reasonably good (R > 0.6). For sea salt the model tended to overestimate the measured concentrations. For elemental carbon the correspondence with black smoke observations was reasonable. However, total PM10 is seriously underestimated, due to unmodelled components (secondary organic aerosols, mineral dust) and missing sources. Therefore, a simple bias correction for four seasons was derived based on the years 2004–2006. The model was compared with the Dutch operational statistical model PROPART and ground-level observations. With bias correction, LOTOS-EUROS performed better than PROPART regarding the timing of events. The major flaw of LOTOS-EUROS was that high values (>50 μg m?3) were still underestimated. Another advantage of LOTOS-EUROS over the statistical model was the more detailed information in space and time, which facilitates communication of the forecast to the general public. 相似文献
996.
Justin M. Langridge R. Joel Gustafsson Paul T. Griffiths R. Anthony Cox Richard M. Lambert Roderic L. Jones 《Atmospheric environment (Oxford, England : 1994)》2009,43(32):5128-5131
The photoenhanced uptake of nitrogen dioxide (NO2) to the surface of commercially available self-cleaning window glass has been studied under controlled laboratory conditions. This material is one of an array of modern building products which incorporate titanium dioxide (TiO2) nanoparticles and are finding increasing use in populated urban areas. Amongst the principal drivers for the use of these materials is that they are thought to facilitate the irreversible removal of pollutants such as NO2 and organic molecules from the atmosphere and thus act to remediate air quality. While it appears that TiO2 materials do indeed remove organic molecules from built environments, in this study we show that the photoenhanced uptake of NO2 to one example material, self-cleaning window glass, is in fact accompanied by the substantial formation (50–70%) of gaseous nitrous acid (HONO). This finding has direct and serious implications for the use of these materials in urban areas. Not only is HONO a harmful respiratory irritant, it is also readily photolysed by solar radiation leading to the formation of hydroxyl radicals (OH) together with the re-release of NOx as NO. The net effect of subsequent OH initiated chemistry can then be the further degradation of air quality through the formation of secondary pollutants such as ozone and VOC oxidation products. In summary, we suggest that a scientifically conceived technical strategy for air quality remediation based on this technology, while widely perceived as universally beneficial, could in fact have effects precisely opposite to those intended. 相似文献
997.
K. Walha R. Ben Amar P. Bourseau P. Jaouen 《Process Safety and Environmental Protection》2009,87(5):331-335
Tuna cooking juice from a Tunisian tuna-processing unit has a high level of polluting load: chemical oxygen demand (COD) is comprised between 4 and 20 g L−1, nitrogen kjedahl (NK) between 0.6 and 3 g L−1 and dry matter between 120 and 160 g L−1. The juice has thus to be treated before being rejected into the environment. This paper considers the nanofiltration (NF) of these concentrated organic/inorganic mixtures using an AFC 30 (NF) membrane. The work focusses on the effect of organic and inorganic matters on the permeate flux and rejections of these matters. For this purpose, mixtures of salt and organic pollution (COD), used as model solutions, were prepared by the dilution of a typical industrial tuna cooking juice. The permeate flux was found to decrease when salt and organic matter concentrations increase. The recovery rate in organic matter decreases with increasing salt or organic matter content and the recovery rate of salt decreases when the COD concentration increases. 相似文献
998.
Using a methodology derived from Economics, the Lorenz Curve and Gini Coefficient are introduced as tools for investigating and quantifying seasonal variability in environmental radon gas concentration. While the Lorenz Curve presents a graphical view of the cumulative exposure during the course of the time-frame of interest, typically one year, the Gini Coefficient distils this data still further, to provide a single-parameter measure of temporal clustering. Using the assumption that domestic indoor radon concentrations show annual cyclic behaviour, generally higher in the winter months than in summer, published data on seasonal variability of domestic radon concentration levels, in various areas of the UK, Europe, Asia and North America, are analysed. The results demonstrate significantly different annual variation profiles between domestic radon concentrations in different countries and between regions within a country, highlighting the need for caution in ascribing seasonal correction factors to extended geographical areas. The underlying geography, geology and meteorology of a region have defining influences on the seasonal variability of domestic radon concentration, and some examples of potential associations between the Gini Coefficient and regional geological and geographical characteristics are proposed. Similar differences in annual variation profiles are found for soil-gas radon measured as a function of depth at a common site, and among the activity levels of certain radon progeny species, specifically 214Bi deposited preferentially in human body-fat by decay of inhaled radon gas. Conclusions on the association between these observed measures of variation and potential underlying defining parameters are presented. 相似文献
999.
1000.